Search results for "chemistry [Arsenates]"
showing 10 items of 2372 documents
The evolution of a dynamic geological system: the support of a GIS for geochemical measurements at the fumarole field of Vulcano, Italy
1997
The island of Vulcano (Aeolian arc, Southern Italy) has displayed several periods of volcanic unrest since the end of the last eruption (1890). We report here results obtained from a long-term survey concerning variations of both the steam output and the exhaling surface area at the summit crater fumarolic field of La Fossa. The field measurements analysed in a Geographical Information System (GIS) show a highly dynamic volcanic system in which deep variations in the geochemistry and the temperature of the released fluids were accompanied by fluctuations in the mass output of steam and the topography of the crater field. The use of a GIS facilitated digitized reconstructions of maps of the …
The southern margin of the Caribbean Plate in Venezuela: tectono-magmatic setting of the ophiolitic units and kinematic evolution
2002
Abstract The southern Caribbean Plate margin in Venezuela consists of a W–E elongated deformed belt, composed of several tectonic units dismembered along the northern part of the South America continental Plate since the Late Cretaceous. The present review, based on petrology and tectono-magmatic significance of each unit, makes it possible to define the main geotectonic elements and to reconstruct the paleogeographic domains from Late Jurassic to Tertiary: (a) Mid-Ocean Ridge Basalt (MORB) proto-Caribbean oceanic basin (Loma de Hierro Unit); (b) oceanic plateau (Dutch and Venezuelan Islands basement); (c) rifted continental margin (Cordillera de La Costa and Caucagua–El Tinaco Units) with …
CO2 release to the atmosphere from thermal springs of Sperchios Basin and northern Euboea (Greece): The contribution of “hidden” degassing
2020
Abstract Greece is a region characterised by intense geodynamic activity that favours the circulation of hydrothermal fluids in the crust transporting volatiles from either the deep crust or the mantle to the surface. Elevated heat flow values are detectable at Sperchios Basin and North Euboea (central Greece), two areas defined by a system of deeply rooted extensional faults and Quaternary volcanic activity. This setting contributed to the formation of numerous hydrothermal systems, which are mostly expressed as CO2-rich thermal springs with intense bubbling. The CO2 output from six bubbling pools has been determined by flux measurements with the use of the floating chamber method. The hig…
Mobility of plume-derived volcanogenic elements in meteoric water at Nyiragongo volcano (Congo) inferred from the chemical composition of single rain…
2017
The chemical composition of single rainfall events was investigated at Nyiragongo volcano (Democratic Republic of Congo) with the aim of determining the relative contributions of plume-derived elements. The different locations of the sampling sites allowed both plume-affected samples (hereafter referred to as “fumigated samples”) and samples representative of the local background to be collected. The chemical composition of the local background reflects the peculiar geographic features of the area, being influenced by biomass burning, geogenic dust, and biological activity. Conversely, fumigated samples contain large amounts of volcanogenic elements that can be clearly distinguished from th…
Flow changes and geochemical anomalies in warm and cold springs associated with the 1992-1994 seismic sequence at Pollina, Central Sicily, Italy
2007
During a three-year discontinuous geochemical monitoring of some warm springs and cold discharges located in central-northern Sicily, some hydro-geochemical changes were observed. Excluding a possible related to a moderate seismic activity were accidentally identified. The observed anomalies showed amplitudes that were modulated by the different geometries and volumes of the feeding aquifers. A poroelastic aquifer contraction, a shaking-induced dilatancy theory as well as seismogenetic-induced changes in the properties of the aquifers have been proposed as possible mechanisms for the water flow and hydro-geochemical changes. These preliminary results could be used to design a monitoring net…
A high resolution record of the last deglaciation in the southern Tyrrhenian Sea: environmental and climatic evolution.
2002
A multidisciplinary study was carried out on core C106 collected in the Salerno Gulf (southern Tyrrhenian Sea). Two tephra layers recovered in the core, N 18 O record of Globigerinoides ruber and Globigerina bulloides and seven 14 C calibrated ages provided the stratigraphic framework. The core sediments cover the last 28 kyr BP. Seismostratigraphic analysis of a high resolution acoustic profile, integrated by the dated core samples, allowed us to reconstruct the architecture and age of sedimentary bodies on the continental shelf. An integrated study based on different taxonomic groups (nannofossils, pteropods, foraminifera, and palynomorphs) provided palaeoclimatic trends, in agreement wit…
Active moss monitoring allows to identify and track distribution of metal(loid)s emitted from fumaroles on Vulcano Island, Italy
2014
Abstract Volatile metal(loid)s are known to be emitted from volcanoes worldwide. We tested the suitability of active moss monitoring for tracking volatile metal(loid)s released from the fumarolic field on Vulcano Island, Italy, and differentiated fumaroles from other sources of gaseous and particulate trace elements such as sea spray and soil. Metal(loid) accumulation on the mosses per day did depend neither on the state of the exposed moss (dead or living) nor exposure time (3, 6, or 9 weeks). After collection, mosses were digested with either HNO3/H2O2 or deionized water and analyzed by ICP-MS. While for most elements both extraction methods yielded similar concentrations, higher concentr…
Late Miocene sea surface salinity variability and paleoclimate conditions in the Eastern Mediterranean inferred from coral aragonite δ18O
2009
Abstract Coral skeletons are archives of chemical proxies which enable paleoenvironmental reconstructions to be made at subannual resolution. Stable oxygen isotope ( δ 18 O) ratios of these archives reflect sea surface temperature (SST) as well as the δ 18 O composition of ambient seawater. The δ 18 O seawater composition is not only controlled by global ice build-up, but river discharge and the hydrological balance of evaporation and precipitation, all influencing sea surface salinity (SSS), also play an important role in marginal seas. New sub-annually resolved coral δ 18 O data were measured and evaluated together with published data from reef coral communities of Late Miocene age from C…
Geothermal energy release at the Solfatara of Pozzuoli (Phlegraean Fields): Phreatic and phreatomagmatic explosion risk implications
1984
The H2O, CO2 and H2S outputs at the Solfatara of Pozzuoli have been measured and a map of the exhaling areas has also been made. The energy released at the surface by the fluids has been estimated to be 1019 ergs/day. The presence of aquifers at Phlegraean Fields increases the phreatic and phreatomagmatic explosion risk. Our results suggest that even if an uprising magma may interact with water at depth, an explosion could occur only at the shallow levels of a few hundred meters. Since the transfer of energy toward the surface is favoured by the presence of fractures, a detailed analysis of the deep fracture network would help to evaluate the risk levels of the various areas of Phlegraean F…
Sweet chestnut (Castanea sativa) leaves as a bio-indicator of volcanic gas, aerosol and ash deposition onto the flanks of Mt Etna in 2005–2007
2009
Sweet chestnut leaves (Castanea sativa) collected from the flanks of Mt Etna volcano in 2005-2007 were analysed by inductively-coupled plasma mass spectrometry to investigate the spatial and temporal variability of element concentrations. The aim of this work was to determine whether these leaves are a bio-indicator for volcanic gas, aerosol and ash deposition and to gain new insights into the environmental effects of quiescent and eruptive volcanic plumes. Results show a positive correlation between sample variability in the concentration of elements in Castanea sativa and enrichment factors of elements in the plume. The spatial and temporal variability of chalcophilic elements (As, Cd, Cu…